| Those of you who are familiar with chemistry and/or metallurgy will probably be familiar with what is called a "cathodic reaction" (also frequently called "electrolysis" or the "battery effect"). Basically, when two metals of different valences come on contact with each other, one metal will end up "stealing" electrons from the other, causing the second metal to corrode at an accelerated rate.
This type of reaction happens between copper and aluminum. The copper "steals" electrons from the aluminum, causing the aluminum to deteriorate. This type of reaction can be a concern in a water cooling system where some of the components are aluminum and some are copper (for example an aluminum radiator and copper water block). Even though the aluminum and copper may not be in direct contact with each other, the water in the system will conduct the electrons from one component to the other.
So how to avoid this? Well, there are several approaches you could take:
1) Use components that are all made of one metal. For example, using a copper water block with a copper-core radiator, or using an aluminum water block with an aluminum radiator.
2) Mix an additive into the water to avoid corrosion. Making a solution of 75% water and 25% automotive antifreeze should help things considerably, although it probably won't stop corrosion completely. Also note that Redline Water Wetter does NOT provide adequate corrosion resistance.
3) Use a coolant other than water. You could use a coolant that is not electrically conductive. Since such coolant does not conduct electricity, it will not carry the electrons from the aluminum to the copper, and the cathodic reaction will not take place. The two most common alternatives to water are alcohol and mineral oil. Unfortunately, alcohol is very volatile and evaporates at a high rate, making it an unsafe coolant. Mineral oil doesn't conduct heat very well, which makes it a poor coolant as well.
4) Place a sacrificial anode in your reservoir (assuming you have a reservoir). You can find sacrificial anodes at most auto parts stores. Basically, what the sacrificial anode does is to "divert" the cathodic reaction. Instead of the aluminum giving up its electrons to the copper, the sacrificial anode will give up its own electrons to the copper, thus protecting the aluminum. However, the sacrificial anode will deteriorate over time and will have to be replaced every so often. |